SRM University-AP is honoured to host Dr Satheesh Ellipilli as a DST- Ramanujan Fellowship Faculty and facilitate his research for the next five years.

Ramanujan Fellowship is one of the most prestigious scientific fellowships that is offered to the Indian scientists working abroad. This fellowship is offered by Science and Engineering Research Board (SERB) to encourage scientists of Indian origin to return and research in an Indian institute/University.

SERB offers the scientists Rs 1,35,000/- per month along with research grant of Rs 7,00,000/- per annum and Rs 60,000/- per annum for overhead charges.

Dr. Satheesh Ellipilli obtained his PhD from Indian Institute of Science Education and Research, Pune. He worked as a postdoctoral researcher in The Ohio State University (Columbus, USA), Emory University (Atlanta, USA), and The University of Utah (Salt Lake City, USA).

Dr. Satheesh Ellipilli has extensive experience in the field of nucleic acid chemistry, particularly, focusing on utilization of RNA nanotechnology for cancer therapy using RNAi therapeutics in combination with small molecule drugs.

He has made numerous publications in some of the most renowned journals like Journal of Organic Chemistry, Journal of Controlled Release, Chemical Communications, Bioconjugate Chemistry, Organic and Biomolecular Chemistry, and Chemical Review to name a few.

Having Dr Ellipilli with us for the duration of his fellowship is a golden learning opportunity and a pleasure to be the host institution for his work. We hope that our students and scholars develop stronger research ethics and acumen in his company.

SRM University-AP could not be more proud to announce that Dr S Mannathan, Head of Department of Chemistry has made it to the top 5% in the list of the Most Cited Authors by the Royal Society of Chemistry. It is inspiring to have a faculty member in our midst whose work has helped and facilitated the research of so many others.

Dr Mannathan obtained his doctorate from National Tsing Hua University, Taiwan. His research interests primarily lie in Metal-catalyzed organic transformation reactions, Multicomponent reactions, and Asymmetric synthesis. His research followed by scientists all over the world leading him to become one of the top 5% authors in terms of citations

In the field of Transition Metal Complexes as Catalysts in Organic Reactions, he particularly leans towards ‘Nickel-and cobalt-catalyzed three-component coupling and reductive coupling reactions’, and ‘Palladium-catalyzed reductive arylation’. Similarly, in Asymmetric Synthesis, he favours research into ‘Asymmetric reductive Heck reaction for the synthesis of chiral indanones’, and ‘Synthesis of bicyclic tertiary alcohols and its related asymmetric version via reductive [3+2] cycloaddition reaction by using chiral cobalt complexes.’

About the top 5% most cited paper:

In this work, he reported the synthesis and application of a Zn-Bp-BTC MOF (Bp – 4,4′-bipyridine; BTC – 1,3,5-benzene tricarboxylic acid; MOF – metal organic framework) as a heterogeneous catalyst for mediating organic reactions. Initial reaction conditions were optimized for the Knoevenagel condensation reaction using Zn-Bp-BTC as a heterogeneous catalyst. Various factors such as the effect of solvent, temperature and catalyst loading were evaluated. Although the reaction proceeded at room temperature using methanol as the solvent, 60 °C offered the best yield in a shorter duration. Under optimized reaction conditions, a wide range of α,β-unsaturated dicyano compounds were prepared from the corresponding carbonyl precursor and malononitrile, the active methylene counterpart. A systematic investigation was also carried out to assess the role of the ligand and metal salt in the Knoevenagel condensation reaction. It was found that the Zn-Bp-BTC MOF catalyzed the reaction efficiently in comparison to its analogue Zn-BTC MOF and precursor Zn(NO 3 ) 2 ·6H 2 O. Finally, catalytic recycling and stability studies showed that the catalyst is able to mediate the reaction for up to five consecutive cycles without undergoing any significant chemical or morphological changes. Further, the catalyst was tested for its efficacy in a multicomponent reaction (MCR). An MCR with the Zn-Bp-BTC MOF as the catalyst afforded good yields and there was no reaction in the absence of the catalyst. Similarly, the catalyst was tested for its efficiency in benzimidazole synthesis.

Dr Mannathan did this research in collaboration with Dr. Kathiresan Murugavel, Scientist, Electro Organic Division, CSIR-Central Electrochemical Research Institute (Govt of India), Karaikudi.

SRM University-AP is pleased to announce that Dr Nimai Mishra, Assistant Professor, Department of Chemistry, SRM University-AP, Andhra Pradesh, along with his research group comprising of students pursuing PhD under him, Mr Rahul Singh, Mr Syed Akhil, and Ms V.G.Vasavi Dutt, has published a research article titled “Shell thickness-dependent photostability studies of green-emitting “Giant” quantum dots” in the journal Nanoscale Advances (The Royal Society of Chemistry) with an impact factor of ~4.533.

About the research:

Highly efficient green-emitting core/shell giant quantum dots have been synthesized through a facile “one-pot” gradient alloy approach. Furthermore, an additional ZnS shell was grown using the “Successive Ionic Layer Adsorption and Reaction” (SILAR) method. Due to the faster reactivity of Cd and Se compared to an analogue of Zn and S precursors it is presumed that CdSe nuclei are initially formed as core and gradient alloy shells simultaneously encapsulate the core in an energy-gradient manner and eventually thick ZnS shells were formed. Using this gradient alloy approach, we have synthesized four different sized green-emitting giant core-shell quantum dots to study their shell thickness-dependent photostability under continuous UV irradiation, and temperature-dependent PL properties of nanocrystals. There was a minimum effect of the UV light exposure on the photostability after a certain thickness of the shell. The QDs diameter of ≥ 8.5 nm shows substantial improvement in photostability compared to QDs with a diameter ≤ 7.12 nm when continuously irradiated under the strong UV light (8 W/cm2, 365 nm) for 48 h. The effect of temperature on the photoluminescence intensities was studied with respect to shell thickness. There were no apparent changes in PL intensities observed for the QDs ≥ 8.5 nm, on the contrary, for example, QDs with < 8.5 nm in diameter (for ~7.12 nm) show a decrease in PL intensity at higher temperatures ̴90°C.

More importantly, these results highlight the synthesized green-emitting gradient alloy QDs with superior optical properties can be used for highly efficient green emitters and are potentially applicable for the fabrication of green LEDs.

Read the full paper: https://pubs.rsc.org/en/content/articlelanding/2021/NA/D1NA00663K

nimai mishraDr Nimai Mishra, Assistant Professor, Department of Chemistry, SRM University-AP, Andhra Pradesh, along with his research group comprising of students pursuing PhD under him, Mr Rahul Singh, Mr Syed Akhil, and Ms V. G. Vasavi Dutt, have published a research article titled “Study of Shell Thickness Dependent Charge Transfer Dynamics in Green Emitting Core/Shell Giant Quantum Dots” Nature Index journal, “Inorganic Chemistry” published by The American Chemical Society having an impact factor of 5.1.

About the paper:

The superior photostability enables green-emitting graded alloy core/shell giant quantum dots (g-QDs) for optoelectronic application. However, it is essential to understand how the shell thickness affects interfacial charge separation. This work explores the impact of shell thickness on photoinduced electron transfer (PET) and photoinduced hole transfer (PHT) with an electron acceptor benzoquinone and a hole acceptor phenothiazine, respectively. The four graded alloy core/shell green-emitting g-QDs with different shell thicknesses were synthesised. The PET and PHT rate constants were obtained from photoluminescence and PL-lifetime decay measurement. Our study concludes that g-QDs with a diameter ~7.14 show a substantial improvement in charge transfer than g-QDs ≥ 8.5 nm in diameter. Similarly, the PET and PHT rates are 3.7 and 4.1 times higher for 7.14 nm g-QDs than for the 10.72 nm sample. The calculated electron and hole transfer rate constant (ket/ht) of g-QD with 7.14 nm in diameter are 10.80 × 107 s-1 and 14 × 107 s-1, which shows 8.5 and 8 times higher compared to g-QDs with a 10.72 nm in diameter.

Industrial implications:

More importantly, these results highlight the impact of shell thickness on the excited state interactions of green-emitting g-QDs and conclude that g-QDs with a relatively thin shell can be a better choice as photoactive materials for photocatalysts, photodetectors, and solar cells.

 

Want the complete details of Dr Nimai Mishra’s paper?

Read the full paper here.

Dr Nimai Mishra, Assistant Professor, Department of Chemistry, SRM University-AP, Andhra Pradesh, along with his research group comprising of students pursuing PhD under his supervision, Ms VG Vasavi Dutt, Mr Syed Akhil, Mr Rahul Singh, and Mr Manoj Paalabathuni have published a research article titled “High-Quality CsPbX3 (X = Cl, Br, or I) Perovskite Nanocrystals Using Ascorbic Acid Post-Treatment: Implications for Light-Emitting Applications” in the Journal “ACS Applied Nano Materials” (published by The American Chemical Society) having an impact factor of ~5.1.

Abstract:

Cesium lead halide perovskite nanocrystals (CsPbX3 PNCs) have been the flourishing area of research in the field of photovoltaic and optoelectronic applications because of their excellent optical and electronic properties. However, they suffer from low stability and deterioration of photoluminescence (PL) properties post-synthesis. One of the ways to minimize the surface defects in the surface treatment with suitable ligands is to achieve the PNCs with superior PL properties for light-emitting applications.

In this article, Dr Mishra’s research group addressed the issue of stability in PNCs. We demonstrate to achieve high photoluminescence and stability of CsPbX3 PNCs by incorporating ascorbic acid via post-treatment as a new capping ligand that is abundantly available. Upon addition of ascorbic acid as surface passivation ligand into the oleic acid/oleylamine system to get near-unity photoluminescence quantum yield (PLQY) of CsPbBr3, CsPb(Br/I)3, and for CsPbI3 perovskite NCs. Maintaining stability has become the hotspot of research in this field. Hence, as-a-proof of concept, the stability studies of PNCs in ambient conditions, under continuous UV irradiation, and PL with temperature variations are put forth here. The stability enhancement with post-treatment of ascorbic acid is highly reproducible as we tested for four batches of samples.

Despite the significant advancements of PNCs, there is a challenge afflicting the stability of CsPbI3 PNCs. They are thermodynamically unstable and undergo a non-perovskite phase (δ-phase) transition at room temperature. Many efforts have been reported in the stabilization of iodide perovskite NCs by critically passivating PNCs and applying them for optoelectronics and photovoltaics. On the other hand, mixed halide perovskites like CsPbBrI2 which are relatively stable than CsPbI3 PNCs are a better choice for device applications. But, photo-induced halide segregation is unavoidable which in turn again limit their usage in practical applications. In this manuscript, we demonstrated that the ultra-stable iodide-based PNCs can be achieved by simple and facile surface treatment with ascorbic acid.

The PL intensity of untreated and ascorbic acid-treated PNCs is recorded for 42 days since the date of synthesis. The measurements are carried out for 4 different batches of samples to ensure reproducibility. It is found that the PL intensity is deteriorating rapidly for untreated PNCs while the PL intensity is largely maintained for ascorbic acid treated PNCs. Nearly ̴72% of the initial PL intensity is maintained even after 42 days for the ascorbic acid-treated CsPbBr3 PNCs while the PL intensity is dropped to 24% for untreated PNCs. Ascorbic acid treated CsPbBrI2 PNCs exhibited exceptional ambient stability where ̴69% of the initial PL intensity is maintained after 42 days while the PL of untreated CsPbBrI2 PNCs is degraded rapidly within 2 weeks from the date of synthesis. Moreover, the PL stability of CsPbI3 PNCs is high for ascorbic acid-treated samples even after 55 days while the PL has deteriorated within 4 days for untreated CsPbI3 PNCs. The PL of untreated CsPbI3 PNCs is completely lost in the first 4 hours of UV illumination while ̴ 76.7% remnant PL is observed for ascorbic acid-treated CsPbI3 PNCs. We believe the stabilization of CsPbX3 PNCs of different halide compositions via simple surface treatment with ascorbic acid could form a basis for futuristic light-emitting applications.

Read the full paper: https://pubs.acs.org/doi/full/10.1021/acsanm.1c04312

microfluidic sers

The Department of Chemistry is glad to announce that Dr J P Raja Pandiyan has published a paper titled ” Microfluidics and surface-enhanced Raman spectroscopy, a win-win combination?” in the journal ‘Lab on a Chip’ having an impact factor of 6.79 in collaboration with researchers from different universities across India, Germany, and Japan.

Abstract of the Research

With the continuous development in nanoscience and nanotechnology, analytical techniques like surface-enhanced Raman spectroscopy (SERS) render structural and chemical information of a variety of analyte molecules in ultra-low concentration. Although this technique is making significant progress in various fields, the reproducibility of SERS measurements and sensitivity towards small molecules are still daunting challenges. In this regard, microfluidic surface-enhanced Raman spectroscopy (MF-SERS) is well on its way to join the toolbox of analytical chemists. This review article explains how MF-SERS is becoming a powerful tool in analytical chemistry. We critically present the developments in SERS substrates for microfluidic devices and how these substrates in microfluidic channels can improve the SERS sensitivity, reproducibility, and detection limit. We then introduce the building materials for microfluidic platforms and their types such as droplet, centrifugal, and digital microfluidics. Finally, we enumerate some challenges and future directions in microfluidic SERS. Overall, this article showcases the potential and versatility of microfluidic SERS in overcoming the inherent issues in the SERS technique and also discusses the advantage of adding SERS to the arsenal of microfluidics.

About the Raman Research Group at SRM AP

Raman spectroscopy, invented by Sir CV Raman in 1928 and got Nobel Prize in 1930, is a vibrational spectroscopic technique that works based on the principle of inelastic scattering of light. Surface-Enhanced Raman spectroscopy (SERS) is one of the modern analytical techniques which can detect chemical and biomolecules in an ultra-low concentration. The research group is working on the development of the SERS technique to address the issues in food, environmental, energy and biological science.

The newly developed SERS substrates are mainly used for the detection of biological samples for disease diagnosis, food samples to ensure food safety, water samples to study the contamination and pollution rate. These studies can make meaningful social changes and improvements.

Amara rajaOnce you are a part of SRM University-AP, we ensure that your future is secured! With the guidance of Dr Sujith Kalluri, Assistant Professor, Electronics and Communication Engineering, Mr Chanakya wends his way to Purdue University, USA, a world-renowned research university, for doing his PhD. He secured admission with a full tuition fee waiver and teaching assistantship. Chanakya Karra spent his two years DST-SERB JRF position at SRM AP and has made remarkable contributions to SRM-Amararaja Centre for Energy Storage Devices.

DST-SERB JRF position helped Chanakya resume his research career, which had a pause for over a year. “It fills me with immense joy to see the SRM-Amararaja Centre for Energy Storage Devices shape up with every possible equipment to conduct research on batteries. Kudos to the management and the efforts of the faculty associated with the centre,” says Mr Chanakya. He further mentioned that the research work conducted at SRM-Amara Raja Centre enabled him to write over three papers that catapulted his chances of admission.

“I would urge the students to make the best use of the opportunities available at SRM-AP and discuss their plans with the faculty. I am sure new avenues will open with the mentoring of world-class faculty at SRM”, says Mr Chanakya to the junior batches of students aspiring for a research career.

Mr Chanakya expressed his gratitude to the faculty members associated with Amararaja Centre for Energy Storage Devices- Dr Pardha Saradhi Maram, Associate Professor, Chemistry, Dr Surfarazhussain S Halkarni, Assistant Professor, Mechanical Engineering, Dr Laxmi Narayana Patro, Assistant Professor, Physics, and others.

Jesni

“Believe you can and you’re halfway there.”Theodore Roosevelt

Jesni M Jacob, currently doing research under Dr Mahesh Kumar Ravva narrates her journey to achieving CSIR-JRF All India Rank of 65 through persistent efforts.

I’m working in the field of computational chemistry on designing and developing organic molecules for OLED applications. Securing an AIR of 65 in the CSIR JRF in Chemical Science June 2021 exam is a dream come true moment for me.

In 2019, I completed my post-graduate studies at Madras Christian College, Chennai. The four-year-long journey from zero to JRF AIR 65 was of hard work, patience, sleepless nights, sacrifices and even frustrated moments. It was challenging to remain motivated after multiple unsuccessful attempts. But I wasn’t ready to give up hope. I believed in myself and dreamed big with faith in God Almighty.

My previous attempts didn’t provide me with any hope of continuing my preparation because my marks were consistently far below the cutoffs. That made me realise one thing: without coaching and ample guidance, qualifying for CSIR JRF is a toiling task for an average student. But I learned that with strong passion, proper dedication, and right strategies of do’s and don’ts, any aspiring student can pass the exam with flying colours.

After each attempt, I learned from my mistakes and tried to optimise my strategies. One should never try to cover the entire syllabus and be bothered about it. I analysed the unit-wise weightage and narrowed it down to a few important topics that I found exciting and comfortable.

Library

  • Choose topics carefully and focus solely on mastering them.
  • Try to stick to and rely on reliable standard textbooks as much as possible.
  • The SRMAP library provided me with excellent access to a wide range of standard texts.

The JRF aspirants should try to solve previous years’ questions from standard exams (CSIR, GATE, IISc, etc.) and note new concepts or approaches every day. Enjoy and prepare short notes with a lot of scribbling and highlighting in various colours. Notes should be concise and simple to revise later. But don’t spend too much time making notes.

I made time for exam preparation along with my work and research activities. I’m grateful to my family, teachers, and especially my guide- Dr Mahesh Kumar Ravva, for their constant support and encouragement. He gave me a safe space to express my desire to ace the exam and my anxieties about it. Dr Mahesh always listened to my concerns and helped me to gain clarity on my thoughts. He always encouraged me to dream big and shared his perspectives and lessons from his life experiences. He is a great mentor, motivator, and teacher to me.

dr vasavi duttThe university revels in its monumental achievement of bringing out the maiden doctorate degree holder, Dr Vasavi Dutt, within four years of its inception. Dr Vasavi Dutt enrolled as a PhD scholar in the Department of Chemistry, under the supervision of Dr Nimai Mishra, Assistant Professor, in 2018. She received the academic honour for her research thesis titled “Improvement of Photoluminescence and Achieving the Stabilization of Cesium Lead Halide Perovskite Nanocrystals for Light-emitting Applications”. Dr Vasavi has been an extremely diligent student and she mustered up immense courage to bring her research to closure even during the testing times of the pandemic.

In the words of Dr Nimai Mishra, “It was a great privilege for me to supervise Ms Vasavi, (correct me Dr Vasavi now) as my first PhD student. She joined my research lab in July 2018 when there was no lab at all, and we started our work at Chemistry BTech Lab”. Dr Mishra was gleaming with pride as he spoke more about his scholar, “During these three and a half years, I had relentless scientific discussions with Vasavi which enriched both of us. Her attitude towards research was remarkable, whenever I gave her a research problem, she used to come up with a detailed outline of how to go ahead with the project”. He also praised her for all her accomplishments which include the publication of 13 research papers, filing of 3 patents and winning the best poster in national & internal conferences.

Dr Vasavi also shared her happiness for having received the mentorship of Dr Mishra, “Working in Dr Nimai Mishra’s lab was a great experience. I had the opportunity to engage and initiate multiple research topics and collaborations. He has always encouraged me to explore new fields to broaden perspectives and bring together new ideas”. She also expressed her gratitude to him for being a welcoming and approachable mentor. “I’m eternally thankful to Dr Mishra for his friendship, empathy, and moreover, for his great sense of humour”. She currently resides in the US with her family. Now that she has successfully completed her PhD, soon she would start looking for a job or rather pursue a post-doctoral fellowship in America.

Dr Vasavi was out of words to thank the university for facilitating and bringing the best in technology and infrastructure for advanced research. “I can never thank my university enough for extending a hospitable environment and nutritious food for all the doctorate students”, she further mentioned. The university serves as a promised land for thousands of research aspirants like her to head towards their dream of making unfeigned contributions to academia.

SRM AP is known for its resources and facilities for pioneering research with the support of global leaders and SME’s while sticking to compliance and international regulations. Obtaining research excellence in every field of study has been a mission of the university. Recently, 50 MSc students from the Department of Chemistry, KBN College, Vijayawada, visited our university to explore the analytical and research facilities available here.

The research areas handled by the Department of Chemistry of SRM AP include the disciplines of chemical sciences, ranging from organic, inorganic, and physical, to theoretical or computational chemistry. The department’s highly disciplinary and collaborative environment is indeed inspiring, and it continues to grab attention. The strong interactions of the university with other premier institutions across India and around the world refine the quality of analytical and research facilities available here. The students from KBN college eagerly interacted with the faculty members and research scholars. Dr Mahesh Kumar Ravva and Dr Rajapandiyan, Faculty members, coordinated the visit.