Dr Nimai Mishra on The Impact of Shell Thickness on Charge Transfer Dynamics in Green Emitting Core/Shell Giant Quantum Dots
Dr Nimai Mishra, Assistant Professor, Department of Chemistry, SRM University-AP, Andhra Pradesh, along with his research group comprising of students pursuing PhD under him, Mr Rahul Singh, Mr Syed Akhil, and Ms V. G. Vasavi Dutt, have published a research article titled “Study of Shell Thickness Dependent Charge Transfer Dynamics in Green Emitting Core/Shell Giant Quantum Dots” Nature Index journal, “Inorganic Chemistry” published by The American Chemical Society having an impact factor of 5.1.
About the paper:
The superior photostability enables green-emitting graded alloy core/shell giant quantum dots (g-QDs) for optoelectronic application. However, it is essential to understand how the shell thickness affects interfacial charge separation. This work explores the impact of shell thickness on photoinduced electron transfer (PET) and photoinduced hole transfer (PHT) with an electron acceptor benzoquinone and a hole acceptor phenothiazine, respectively. The four graded alloy core/shell green-emitting g-QDs with different shell thicknesses were synthesised. The PET and PHT rate constants were obtained from photoluminescence and PL-lifetime decay measurement. Our study concludes that g-QDs with a diameter ~7.14 show a substantial improvement in charge transfer than g-QDs ≥ 8.5 nm in diameter. Similarly, the PET and PHT rates are 3.7 and 4.1 times higher for 7.14 nm g-QDs than for the 10.72 nm sample. The calculated electron and hole transfer rate constant (ket/ht) of g-QD with 7.14 nm in diameter are 10.80 × 107 s-1 and 14 × 107 s-1, which shows 8.5 and 8 times higher compared to g-QDs with a 10.72 nm in diameter.
Industrial implications:
More importantly, these results highlight the impact of shell thickness on the excited state interactions of green-emitting g-QDs and conclude that g-QDs with a relatively thin shell can be a better choice as photoactive materials for photocatalysts, photodetectors, and solar cells.
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- Published in Chemistry-news, Departmental News, News
Ms Tanoogna bags three gold medals at National Indoor Archery Championship-2021
Mallarapu Tanoogna, a third-year civil engineering student at SRM University-AP, has excelled at National Indoor Archery Championship-2021, winning three gold medals and finishing 8th in the National Open Ranking, representing Andhra Pradesh. The National Field Archery Development & Welfare Association in Salem, Tamilnadu, hosted the inaugural National Indoor Archery Championship-2021 on 25th and 26th December. Archery players from the South Indian states of Kerala, Tamil Nadu, Karnataka, Andhra and Telangana participated in the competition.
Ms Tanoogna, representing Andhra Pradesh from SRM AP has been training to participate in indoor and outdoor archery championships for a year. She won gold medals in the Senior Recurve women individual, women team and mixed team categories and is ranked 8th in the national archery rankings.
“It is a pride moment that our student wins gold medals and opens national ranking,” said university Vice-Chancellor-Prof V S Rao, congratulating Ms Tanoogna. Registrar-Dr R Premkumar, Deans, and faculty members congratulated Ms Tanoogna and promised her all the support for attending more national and international championships in the future.
- Published in CIVIL NEWS, News, Students Achievements
STEM-Research Society Best Paper Award to faculty and undergraduate students
“As an undergraduate student, I initially faced many difficulties selecting the area of interest, analysing and organising a paper, and academic writing skills. The continuous support from faculty at SRM university-AP helped me overcome these issues. This achievement would have been impossible without the support and efforts of my faculty mentors. My heartful gratitude to Dr Shubh Lakshmi madam and Dr Tousif Khan N sir for their kind support and encouragement in research work. I am grateful to start my research career under their guidance. Also, the management encourages and supports us every time in every possible way by providing scholarships.”
–Pendem Manoj Sai
A paper titled “Exhaustive Search Approach to Place PV in Distribution Network for Power Loss Minimization” has been awarded STEM-Research Society Best Paper Award in the recently held conference, Soft Computing: Theories and Applications (SoCTA)-2021, at the Indian Institute of Information Technology, Kota on the dates December 17-19, 2021. The authors of the paper are- P Manoj Sai, M Dhana Sai Baji, Dr Shubh Lakshmi, and Dr Tousif Khan Nizami from the Department of Electrical and Electronics Engineering, School of Engineering and Sciences, SRM University-AP, Andhra Pradesh, India. The paper is selected for publication in Lecture Notes in Networks and Systems, Springer (Indexed in SCOPUS).
This paper proposes an exhaustive search approach to determine the best location and size of PV placement for power loss minimisation of radial distribution networks. In this approach, the network power loss is determined by placing PV in each location, one at a time, and the size of PV in the same location is varied between a set minimum and maximum limits. The combination of location and size of PV, which provide the minimum network power loss, can be the best location and size of PV for power loss minimisation of radial distribution networks. The forward-backwards sweep load flow algorithm with the PV model is used to determine the power loss for each combination of location and size of PV.
The paper was presented by Mr P Manoj Sai, a BTech EEE 4th year student from SRM University-AP, Andhra Pradesh. He is thrilled to receive the best paper award and extended his gratitude to Dr Tousif Khan N, the Head of the Department, and Dr Shubh Lakshmi, Assistant professor in the Department of Electrical and Electronics Engineering, for their continuous guidance. Further, he extended his thanks to the management and Pro Vice-chancellor of SRM University-AP for providing financial support.
- Published in Departmental News, EEE NEWS, News, Students Achievements
Welcoming 2022 with joy, hope, and fun
On Saturday morning, students, faculty and administrative staff members at SRM University-AP welcomed the new year with colourful celebrations on campus. Vice-Chancellor Prof V S Rao cut the New year special cake and addressed the gathering. “We shall enter the new year with the hope that pandemic will be endemic in 2022”, he said. He also suggested that everyone take steps in a planned manner to receive the success they hope for in the new year.
Dr R Premkumar, the Registrar, expressed hope that the university would move towards higher standards under the supervision of Professor B V Babu, Dean of the School of Engineering and Sciences. The organisers and participants of the event and various game activities adhered strictly to the Covid-19 protocol. Prizes were given away to the winners of various competitions.
The event was attended by Registrar-Dr R Premkumar, Dean-Prof B V Babu, Controller of Examinations- Dr Vinayak Kalluri, Directors-Mrs Suma N, Dr K Mohan, Wg Cmdr Venkataachalam Sekkappan, Prof Y Siva Sankar and others.
Journey of Dr Manjula R towards Privacy in Wireless Sensor Networks
Anecdote:
“Since my school days, I have been fascinated by writing cryptic text, though intelligible. It all started with mirror-writing the teaching-feedback that was requested by our class teacher Tr. Jezuine. Once the feedback was read, the teacher called me and asked: “How did you learn this?” I was on cloud nine and replied, “it just happened only for you”, with a massive smile on my face. Later, I never thought of any secret writing for a while. It was only during the initial days of my teaching profession; I had the opportunity to read my classmate’s notes scribbled in a cryptic text which triggered further enthusiasm in me. So, during my postgraduate course, I started reading and presenting seminars on Cryptography and Security. This further led to deeper digging into the core of security aspects that also led to a trivial postgraduate project on key-establishment in wireless sensor networks. Later during the research period, I chose a new upcoming area – wireless sensor networks (broader domain), and contextual- and content- privacy (narrower domain) – privacy preservation in WSNs as my research topic.”
-Dr Manjula R
The Issue:
The significance: The privacy of individuals is being compromised gradually with the increasing popularity and rapid deployment of pervasive computing technologies. The benefits and conveniences offered by modern devices often lead people to neglect the dire consequences of possible privacy violations. Therefore, privacy risks should be taken into considerations while designing responsible technologies. One such technology that poses serious privacy risks is the Wireless Sensor Networks (WSNs). Despite the enormous benefits offered by WSNs to humanity, several issues need meticulous attention. Security and privacy are such issues in WSNs. For instance, the US military aims to adopt Internet of Things (IoT) enabled WSN. The usage of WSNs, Unmanned Aerial Vehicles (UAVs), tiny robots (nanoscale robots) are envisioned to transform the battlefield scenario. In particular, these digital devices and components are embedded in soldiers’ uniforms to collect the health status of the worriers and relay this information to a central controller, named the base station (BS). The BS is located near places where the internet is easily accessible. Nevertheless, WSNs are deployed in areas where it is challenging to have internet. However, this problem is easily solved with the amalgamation of WSNs and IoT. This comes with unwelcoming consequences. The unattended nature of these networks provides an attacker with physical access to the devices. The attacker may compromise the node and conduct illegal activities, say, mimic fake chemical leakages etc. Furthermore, the broadcast nature of the transmission medium gives access to the packets exchanged by the sensor nodes to anyone within the communication range. Consequently, adversaries may exploit these features of WSNs in order to launch attacks against the network and thus render all the potential benefits offered by this technology unusable. Hence, privacy preservation in WSNs is a significant issue that needs to be addressed to safeguard personal and private assets—soldiers or endangered animals etc.
In a quest to provide countermeasures to such attacks, Dr Manjula R and her team are developing privacy preserved solutions with particular emphasis on routing in WSNs. Their recent research article titled “Protecting Source Location Privacy in IoT Enabled Wireless Sensor Networks: The Case of Multiple Assets” has been accepted for publication in a peer-reviewed journal – IEEE Internet of Things Journals. This work is co-authored by Prof. Raja Datta, IIT Kharagpur and Mr Tejodbhav Koduru (studying in 5th semester in dept. of CSE, SRM University AP). The SCI-indexed journal has an impact factor of 9. 396. The team is also focusing on the development of new countermeasures to mitigate eavesdropping attacks in WSNs.
Dr Lakhveer Singh published in Advanced Functional Materials for Engineered Nanoenzymes
The Department of Environmental Science is proud to announce that Dr Lakhveer Singh has published his paper titled, “Engineered Nanoenzymes with Multifunctional Properties for Next-Generation Biological and Environmental Applications” in Advanced Functional Materials with an impact factor of 18.50.
About the Paper:
Enzyme mimicking studies took on a new aspect as it turns out that inorganic nanomaterials could have intrinsic enzyme-like activities. The word nanozyme (nanoenzyme) was first coined to describe the ribonuclease-like activity of ligand functionalised gold nanoparticles in 2004. Since then, various research has been continued on nanomaterials with enzyme-like activity. Thus, nanoenzyme has come to describe nanomaterials with enzyme-like activity.
Abstract:
As a powerful tool, nanoenzyme electrocatalyst broadens the ways to explore bioinspired solutions to the world’s energy and environmental concerns. Efforts to fashion novel nanoenzymes or engineering nanoenzymes for effective electrode functionalisation is generating innovative, viable catalysts with high catalytic activity, low cost, high stability and versatility, and ease of production. High chemo-selectivity and broad functional group tolerance of nanoenzyme with an intrinsic enzyme-like activity make them an excellent environmental tool. The catalytic activities and kinetics of nanoenzymes that benefit the development of nanoenzyme-based energy and environmental technologies by effectual electrode functionalisation are discussed in this article. Further, deep insight on recent developments in the state-of-art of nanoenzymes either in terms of electrocatalytic redox reactions (viz. oxygen evolution reaction, oxygen reduction reaction, nitrogen reduction reaction and hydrogen evolution reaction) or environmental remediation/treatment of wastewater/or monitoring of a variety of pollutants. The complex interdependence of the physicochemical properties and catalytic characteristics of nanoenzymes are discussed, along with the exciting opportunities presented by nanomaterial-based core structures adorned with nanoparticle active-sites shell for enhanced catalytic processes. Thus, such modular architecture with multi-enzymatic potential introduces an immense scope of making its economical scale-up for multielectron-fuel or product recovery and multi-pollutant or pesticide remediation as reality.
Collaboration:
The assignment on “Engineered Nanoenzyme” was completed with the Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-Ro, Yuseong-Gu, Daejeon 34141, the Republic of Korea, along with other universities.
Social and Industrial Implications:
Trends of nanoenzyme are replacing conventional enzymes, particularly in a microbial bioelectrofuel biosystem, as cheap and efficient electrocatalysts. In this account, various strategies from altering scaffold to point alteration and iterative targeted tailoring have been applied to improve the enzyme-like activity and selectivity of the artificial enzymes.
Future Plans:
Strategies need to be devised to increase the mass loading of both homogenous and heterogeneous nanoenzyme for higher current density. Though, area of nanoenzyme is in its growing stage, engineering nanoenzyme with improved catalytic performance comparable to or even higher than that of the natural enzyme is one of the most concerning issues at this moment. Besides, the future breakthrough in nanoenzyme technology will lead to the development of novel catalysts with wider applications in multiple disciplines.
- Published in Departmental News, ENVS News, News
Dr Ipsita Pradhan
- Published in Assistant Professor, Faculty, SLASS
Dr Subhankar Ghatak
- Published in Assistant Professor, CSE Faculty, Faculty, SEAS
Innovation for sustainable smart solutions
Speakers from across the globe are invited for the International Lecture Series organised by the Office of International Relations and Higher Studies, SRM University-AP. The latest session of the series aims to provide insight into how new technological developments are changing the face of society. Mr Werner Fischer, Sustainable Development Consultant, will engage the participants on the topic “Innovation for Sustainable Smart Solutions” on January 10, 2022, at 11.30 am.
The lecture aims to provide a multidisciplinary approach to environmental studies, urban planning, and development. Focus on inventive technical developments is essential for the establishment of sustainable green societies. Such conversations with experts intend to challenge academic norms, examine established knowledge-power relationships, and shine a light on issues of equality, equity, diversity, and inclusion.
Speaker’s Profile:
Mr Werner Fischer, Sustainable Development Consultant
Co-Author of “How to Create Smart Villages” book
Advisor at Brightmind.io
Advisor at UC Berkeley-led private-public sector, Rebuilding India Initiative.
Worked as a Director of research for the Smart Village Movement in India
BSc in Business Studies and Economics from the University of Konstanz
MSc in Technology Management (M.Sc.) from the Braunschweig University of Technology, Germany
Business Studies at University of California, Berkeley, Haas School of Business
All are invited to join the session on January 10, 2022, at 11.30 am.
Master Your Emotions with Miss Liza Hazarika
When something good happens we feel joyous. When something bad happens we feel sad and gloomy. It is natural and healthy to feel. But what if what we are feeling is preventing us from achieving our best. We cannot abandon important tasks in face of stronger emotions. We need to learn master our emotions.
Tune in for this session on mastering your emotions with Miss Liza Hazarika to learn to keep yourself centred at all times and live a happy, healthy, and productive life.
Date: January 08, 2022
Time: 5.00 pm IST
- Published in Events