Professors Develop Fish Scale SERS Substrates for Pollutant Detection
Surface-Enhanced Raman Spectroscopy (SERS), a technique that helps scientists detect tiny amounts of substances, is used for checking pollutants in our environment and the food we eat. However, using this method can be tricky because sometimes other substances can interfere. To overcome these challenges, scientists are working on better ways to prepare samples and analyse the data with a quick and easy way to find harmful pollutants called PFOSA in human urine, soil, and water using a fish scale-based substrate. This remarkable research titled, “Ag nanoparticle-embedded fish scales as SERS substrates for sensitive detection of forever chemical in real samples” by faculty members from the Department of Chemistry and Department of Biological Sciences, Dr J P Raja Pandiyan and Dr Anil K Suresh, along with their research scholars, Ms Jayasree K and Ms Arunima J, have opened up new avenues, demonstrating a significant advancement in the field of science.
Abstract:
Surface-enhanced Raman spectroscopy (SERS) has emerged as one of the most promising analytical tools in recent years due to its advantageous features such as high sensitivity, specificity, ease of operation, and rapid analysis. These attributes make SERS particularly well-suited for environmental and food analysis. However, detecting target analytes in real samples using SERS faces several challenges, including matrix interference, low analyte concentrations, sample preparation complexity, and reproducibility issues. Additionally, the chemical complexity of pollutants and environmental factors can impact SERS measurements. Overcoming these hurdles demands optimised experimental conditions, refined sample preparation methods, and advanced data analysis techniques, often necessitating interdisciplinary collaborations for effective analysis. Therefore, our focus lies in the development of various methods for fabricating SERS substrates, pretreating analytes, and devising sample preparation strategies. These efforts aim to enable the detection of analytes like Perfluorooctane sulfonamide (PFOSA) – a toxic environmental pollutant within complex real samples, including human urine, lake water, and soil samples.
Practical / Social Implications:
SERS Community: Introducing a facile fabrication method for developing filter paper-based substrates, utilizing evaporation-induced self-assembly methods with the aid of 96-well plates. These substrates boast exceptional sensitivity and uniformity, exhibiting a relative standard deviation (RSD) of 8.2%. They offer easy fabrication and serve as effective SERS substrates for various applications.
Industry and Government Bodies: This invention plays a pivotal role in assessing contamination in food and water bodies, serving as a crucial tool in monitoring
environmental contamination through on-site analysis with portable instruments. It ensures adherence to regulatory standards and safeguards public health.
Research: Beyond its practical applications, the invention supports scientific research endeavours focused on identifying microplastic contaminants in real-world samples using portable Raman spectrometers. This not only aids ongoing research but also paves the way for future studies in this critical field.
Collaborations:
1. Dr Hemanth Noothalapati Raman Project Center for
Medical and Biological
Applications, Shimane
University, Matsue 690-8504,
Japan
2. Dr Murali Krishna C. Advanced Centre for
Treatment, Research and
Education in Cancer, Tata
Memorial Centre, Navi
Mumbai 410210, India
3. Dr Soma Venugopal University of Hyderabad, India
Future Research Plans:
Harnessing SERS for the Detection of Emerging Contaminants in Environmental and Food Matrices
- Published in Chemistry-news, Departmental News, News, Research News
Dr Jaidev Advances Green Chemistry with New Acetic Acid Production Technique
In a remarkable contribution to the field of green chemistry, Dr Jaidev Kaushik, Assistant Professor in the Department of Chemistry, has published a significant research paper titled “Green Light Promoted Photoreduction of Carbonate to Acetic Acid by Zinc Ash-Derived ZCu@ZnO” in the prestigious Q1 journal, ACS Sustainable Chemistry & Engineering, with an impressive impact factor of 7.1.
Dr Kaushik’s research addresses the pressing need for sustainable methods of producing acetic acid, a widely used chemical in various industrial applications. The study explores an innovative photoreduction process that utilises green light to convert carbonate compounds into acetic acid using a novel catalyst derived from zinc ash. This approach not only showcases the potential for an eco-friendly production method but also emphasises the recycling of zinc waste, turning a byproduct into a valuable resource.
The paper highlights the efficiency of Zinc Ash-Derived ZCu@ZnO as a catalyst in the photoreduction process, demonstrating its effectiveness under green light conditions. The findings could pave the way for more sustainable practices in chemical manufacturing, aligning with global efforts to reduce carbon emissions and promote environmentally friendly technologies.
This publication underscores the commitment of SRM University – AP to fostering innovative research that addresses contemporary environmental challenges. Dr. Kaushik’s work exemplifies the university’s focus on sustainability and its aspiration to lead in the field of scientific research.
As the demand for sustainable chemical processes grows, Dr Kaushik’s research will likely inspire further investigations and developments in green chemistry, contributing to a more sustainable future.
Abstract of the Research
Mineralized carbon (carbonate) is the readily available carbon dioxide (CO2) source in acidic aqueous conditions. The photoreduction of carbonate to value-added hydrocarbons could be a novel finding performed in the presence of monochromatic visible light and waste-derived photo-active nanomaterials. In this report, we have synthesized ZnO particles from the zinc ash generated as waste in the galvanization process in the steel industry; ZnO particles were decorated with CuO nanoparticles and then further activated by reducing them to get a heterojunction photocatalyst (ZCu@ZnO). After that, ZCu@ZnO is utilized to photoreduce carbonate to acetic acid (AcOH) in a peroxy-rich solvent as a hydrogen-rich solvent under various monochromatic light sources and sunlight. Additionally, different physical and chemical parameters, such as solvent mixture, light sources, photocatalysts, time, etc., were optimized to get the maximum yield of AcOH under monochromatic light of 525 nm wavelength (Green light).
Explanation of the Research in Layperson’s Terms
This report is proposing the solution of two problem statements; first, utilization of zinc ash generated as a by-product after galvanization process; and second, cost-effective and energy efficient process for conversion of carbonates to value-added C2 hydrocarbon.
Practical Implementation and the Social Implications associated with the Research
The process adds value by converting low-value waste into high-value nanomaterials, potentially offering new revenue streams for recycling and waste management industries. It supports the principles of a circular carbon economy and green chemistry focusing on synthesis of hydrocarbons from carbonates.
Collaboration
Dr Sumit Kumar Sonkar (MNIT Jaipur, India)
Future Research Plans
1. The adsorption/photodegradation-assisted quick and efficient removal of next generation advanced pollutants such as microplastic, pesticides, pharmaceutical waste, etc. by hydrophobic carbon aerogel and their doped and functionalized versions.
2. Utilizing waste derived heterogeneous catalysts in organic transformation reactions.
3. Selective sensing of toxic metal ions/biomarkers/biomolecules using fluorescent nanomaterials.
4. Upcycling of carbonates/CO2 via photo/thermal assisted catalyzed reactions to get C1 and C2 hydrocarbons (green fuel).
- Published in Chemistry-news, Departmental News, News, Research News
Dr Jaidev Kaushik’s Publishes New Publication on Graphene Incorporated Aerogels
Dr Jaidev Kaushik, an Assistant Professor in the Department of Chemistry, has recently published a pioneering research paper in the prestigious journal Langmuir (ACS). The paper, titled “Graphene Incorporated Sugar-derived Carbon Aerogel for Pyridine Adsorption and Oil-Water Separation,” explores innovative applications of graphene-based materials.
Dr Kaushik’s research focuses on the development of a novel carbon aerogel derived from sugar and incorporated with graphene. This material demonstrates exceptional efficiency in adsorbing pyridine, a harmful organic compound, and effectively separating oil from water. These findings hold significant promise for environmental remediation and industrial applications, offering a sustainable solution to pollution and waste management challenges.
The publication of this paper in Langmuir highlights the cutting-edge research being conducted at SRM University-AP and underscores Dr Kaushik’s contributions to the field of chemistry. His work not only advances scientific understanding but also paves the way for practical applications that can benefit society at large.
Abstract
In this report, we have synthesized three-dimensional and hydrophobic graphene-incorporated carbon aerogel (G-SCA) derived from sugar. G-SCA is being used as a multifunctional sorbent material for removing various advanced water soluble and insoluble pollutants Initially, G-SCA is being explored for the adsorption of nitrophenols, nitroaromatics (3-nitroaniline), insecticide (Phoskill), antibiotic (ciprofloxacin), and pharmaceutical drug precursor (pyridine). Later, same G-SCA is also explored in the absorption of various protic and aprotic organic solvents and oils (including crude oil, waste cooking oil, and waste Mobil oil), with excellent recyclability checked up to 10 cycles. Moreover, oil-water separation experiments are also being done in various industrial wastewater samples and seawater to support the real-life accessibility of present approach. Large-scale applicability of G-SCA is also checked by performing crude oil-seawater separation experiments using a laboratory-scale prototype demonstrating the successful continuous recovery of crude oil.
Explanation of The Research in Layperson’s Terms
This research demonstrates the synthesis of carbon aerogel from edible sugar followed by the incorporation of graphene oxide to make a near superhydrophobic and good water-floating sorbent material. Later, this sorbent material was used to decontaminate wastewater from advanced pollutants such as explosive wastes, expired antibiotics, pharmaceutical waste, insecticides, etc. This report also showed the practical demonstration of crude oil recovery from seawater, thus contributing to the circular economy process.
Title of Research Paper in the Citation Format
F. Agrawal, K. Gupta, J. Kaushik, K. M. Tripathi, S. K. Choudhary, S. K. Sonkar, Graphene Incorporated Sugar Derived Carbon Aerogel for Pyridine Adsorption and Oil–Water Separation, Langmuir 2024, 40, 18028–18038.
Practical Implementation or the Social Implications Associated with the Research
This work describes the synthesis of low-cost near superhydrophobic carbon aerogel, displaying its multiple applications in wastewater treatment from water-soluble and water-insoluble pollutants. It is also an alternative and cost-effective approach for recovering valuable oil and organic compounds from water rather than degrading or destroying them so they can be reused.
Collaborations
Dr Sumit Kumar Sonkar (MNIT Jaipur, India)
Future Research Plans
1. The adsorption/photodegradation-assisted quick and efficient removal of next generation advanced pollutants such as microplastic, pesticides, pharmaceutical waste, etc. by hydrophobic carbon aerogel and their doped and functionalised versions.
2. Utilizing waste derived heterogeneous catalysts in organic transformation reactions.
3. Selective sensing of toxic metal ions/biomarkers/biomolecules using fluorescent nanomaterials.
4. Upcycling of carbonates/CO2 via photo/thermal assisted reactions to get C1 and C2 hydrocarbons (green fuel).
- Published in Chemistry-news, Departmental News, News, Research News
Exploring Inventive Methods to Detect Microplastics in Contaminated Products
The Department of Chemistry is glad to announce that Dr Rajapandiyan Panneerselvam, Associate Professor, Ms Jayasree K, Research Scholar, and Ms Mounika Renduchintala, BSc student, have had their breakthrough research published as a patent titled “A Method for Detecting Microplastics from Contaminated Products” with Application Number: 202441045388. Various research has been undertaken by scientists in developing improved methods for sample preparation and data analysis, aiming to reliably detect pollutants like microplastics in complex samples such as sea salt, soil, and water. In line with these efforts, this patent introduces a rapid and easy method to detect microplastics in contaminated products and water bodies using a filter paper-based substrate.
Abstract
Surface-enhanced Raman spectroscopy (SERS) has emerged as one of the most promising analytical tools in recent years due to its advantageous features, such as high sensitivity, specificity, ease of operation, and rapid analysis. These attributes make SERS particularly well-suited for environmental and food analysis. However, detecting target analytes in real samples using SERS faces several challenges, including matrix interference, low analyte concentrations, sample preparation complexity, and reproducibility issues. Additionally, the chemical complexity of pollutants and environmental factors can impact SERS measurements. Overcoming these hurdles demands optimized experimental conditions, refined sample preparation methods, and advanced data analysis techniques, often necessitating interdisciplinary collaborations for effective analysis. Therefore, our focus lies in the development of various methods for fabricating SERS substrates, pretreating analytes, and devising sample preparation strategies. These efforts aim to enable the detection of analytes like microplastics within complex real samples, including sea salts, soil samples, lake water, and various food products.
Practical Implementation/ Social Implications of the Research
SERS Community: Introducing a facile fabrication method for developing filter paper-based substrates, utilizing evaporation-induced self-assembly methods with the aid of 96-well plates. These substrates boast exceptional sensitivity and uniformity, exhibiting a relative standard deviation (RSD) of 8.2%. They offer easy fabrication and serve as effective SERS substrates for various applications.
Industry and Government Bodies: This invention plays a pivotal role in assessing contamination in food and water bodies, serving as a crucial tool in monitoring environmental contamination through on-site analysis with portable instruments. It ensures adherence to regulatory standards and safeguards public health.
Research: Beyond its practical applications, the invention supports scientific research endeavors focused on identifying microplastic contaminants in real-world samples using portable Raman spectrometers. This not only aids ongoing research but also paves the way for future studies in this critical field.
Collaborations
- Dr Hemanth Noothalapati – Raman Project Center for Medical and Biological Applications, Shimane University, Japan
- Dr Murali Krishna C – Advanced Centre for Treatment, Research and Education in Cancer, Tata Memorial Centre, Navi Mumbai, India
- Dr Soma Venugopal – University of Hyderabad, India
The research team hopes to develop a novel SERS substrate for the detection of environmental pollutants in real-world samples.
- Published in Chemistry-news, Departmental News, News, Research News
A Novel SERS Substrate to Detect Food Contamination
Dr Rajapandiyan P, Associate Professor, Department of Chemistry, and his PhD scholar, Ms Arunima Jinachandran, recently filed and published a patent, “A Substrate for Contaminant Detection and a Process for its Synthesis,” with Application Number: 202441043642 in the Patent Office Journal. The research duo has developed a novel SERS (Surface-Enhanced Raman Spectroscopy) substrate by synthesising silver nanopopcorn and depositing it on a polycarbonate membrane.
This novel substrate demonstrates excellent uniformity, reproducibility, and mechanical stability. It is used for the sensitive detection of toxic antibiotic nitrofurazone on fish surfaces and in honey. This breakthrough could significantly enhance food safety monitoring by providing a reliable and efficient method for detecting harmful substances.
Abstract
Detecting nitrofurazone (NFZ) in aquaculture and livestock is crucial due to its carcinogenic properties. This study presents a flexible polycarbonate membrane (PCM) with three-dimensional silver nanopopcorns (Ag NPCs) for NFZ detection on fish surfaces using surface-enhanced Raman spectroscopy (SERS). The Ag-NPCs/PCM substrate demonstrates a significant Raman signal enhancement (EF = 2.36 × 106) due to hotspots from nanoscale protrusions and crevices. It achieves a low limit of detection (LOD) of 3.7 × 10−9 M, with uniform and reproducible signals (RSD < 8.34%) and retains 70% efficacy after 10 days. The practical detection LODs for NFZ in tap water, honey water, and on fish surfaces are 1.35 × 10−8 M, 5.76 × 10−7 M, and 3.61 × 10−8 M, respectively, demonstrating its effectiveness for various samples. This Ag-NPCs/PCM substrate offers a promising approach for sensitive SERS detection of toxic substances in real-world applications.
Practical Implementation/ Social Implications of the Research
The practical applicability of the proposed Ag-NPCs/PCM SERS substrate is validated by successfully detecting NFZ in various actual samples, such as tap water, honey water, and irregular fish surfaces.
Collaborations – Prof. Tzyy-Jiann Wang – National Taipei University of Technology, Taiwan
Dr Rajapandiyan and Ms Arunima will continue to work towards the development of novel flexible SERS substrates for detecting toxic pollutants in food.
- Published in Chemistry-news, Departmental News, News, Research News
“Nano Jatha”: A Pathway to Nanoscience and Technology
As part of the 13th edition of the Bengaluru India Nano 2024, heralded by Bharat Ratna recipient and renowned chemist Prof. C N R Rao, SRM University-AP hosted “Nano Jatha“, an intensive science outreach programme, catering to educate undergraduate graduates on the emerging trends of nanotechnology, on July 20, 2024. The Nano Jatha programme organised, aimed to raise awareness on nanoscience and technology through technical presentations by expert scientists and a distinctive live experiment demonstration of nano kits focused on showcasing nanoscience ideas.
The event featured two expert talks by eminent dignitaries. Prof. B L V Prasad, Director-Centre for Nano and Soft Matter Sciences (CeNS), Department of Science and Technology, Govt. of India, also serving as the Nodal Officer for organising Nano Jatha events, delivered a session on the introduction to nanoscience and technology. “Nanoscience and technology are often foretold as the technology of the future. This multidimensional technology will revolutionise our understanding of every natural phenomenon and every aspect of human life,” remarked Prof. Prasad in his session.
Prof. C P Rao, Senior Professor at the Department of Chemistry, presented the second expert talk on the applications of nanomaterials. The session delved into the properties of covalent molecules and its assemblage leading to cutting-edge technology. The programme also featured an exhibition were experiments on Gold nanoparticle; Galvanization reaction between metals; Piezoelectric pavement for futuristic applications; Humidity sensors for real-world applications and many more were displayed.
Prof. C V Tomy, Dean-School of Engineering & Sciences and Dr Pardha Saradhi Maram, Head-Department of Chemistry, emphasised that the Nano Jatha exemplified the university’s commitment to hands-on learning in science, specifically nanotechnology.They commented that the Department of Chemistry is dedicated to fostering scientific knowledge and igniting passion for chemistry among students and educators alike and will continue to organise events like Nano Jatha, conferences, workshops, and Faculty Development Programmes to achieve the same.
Over 300 students from 7 regional colleges in Andhra Pradesh participated in the programme, displaying their zeal in the discussions and nano kit demonstrations. The event was well executed benefitting the student community significantly in understanding various emerging fields in science and technology.
- Published in Chemistry-news, Departmental News, News
Dr Chinmoy Das’s Groundbreaking Research Unveils Promising Discoveries
Dr Chinmoy Das, Assistant Professor at the Department of Chemistry at SRM University-AP, has made an impactful contribution with the publication of his research paper, “Insights into the Mechanochemical Glass Formation of Zeolitic Imidazolate Frameworks” in the prestigious Angewandte Chemie International Edition with an impact factor of 16.6. His paper unveils a rapid, eco-friendly, and efficient mechanochemical approach to transform glasses from their crystalline zeolitic imidazolate frameworks. This pioneering work opens new doors for sustainable and effective glass formation, showcasing the power of innovation in the field of chemistry.
Abstract:
We describe a rapid, ecofriendly, and efficient mechanochemical approach to transform glasses from their crystalline zeolitic imidazolate frameworks (ZIFs). We exposition mechanochemical technique through which the traditional melt-quench preparation of glassy phases can be replaced. In this study, we explore that Zn(II), Co(II), and Cu(II)- based crystalline ZIFs transformed into the glassy phases within five minutes through the mechanical ball milling technique. The appearance of glass transition temperature(T g ) upon mechanical milling of crystalline states demonstrated by different characterization techniques, such as X-ray powder diffraction (XRPD), differential scanning calorimetry (DSC), simultaneous thermogravimetric and differential thermal analyses (TG/DTA), scanning electron microscopy (SEM), X-ray total scattering and its deduced pair distribution functions (PDFs). We characterized the porosity and density of the glassy phases through CO 2 gas sorption techniques which aligned with the observation of thermal, structural, and textural features of the ZIFs after varying ball milling times beyond five minutes.
Practical implementation
We can prepare bulk ZIF glasses within five minutes of the mechanochemical approach that will guide the greater feasibility to produce the glass materials for industrial implications. In addition, the greater the accessibility of glassy materials, the greater the fabrication of glassy materials-based device fabrication.
Collaborations
This article has been published with the collaboration of Prof. Sebastian Henke (Henke Group), Department of Chemistry and Chemical Biology, TU Dortmund University, Dortmund, Germany.
Future Research Plans
Recently, we established our research group in SRM University-AP, and our group has started to explore an emergent research area of crystal-glass composite materials towards the applications of atmospheric water harvesting, solid-state electrolytes (Alkali and Alkaline metal ions-based), photovoltaics, and conversion of gaseous Carbon-dioxide molecules to industrially relevant liquids, such as methanol or ethanol.
- Figure 1. (A) Single crystal structures of various ZIFs indicated in the figure. (B) Schematic representation of the traditional route to ZIF glass formation (red line) and the mechanochemical vitrification approach followed in this work (blue line). (C) PXRD patterns of the pristine ZIF polycrystalline materials and after five minutes of mechanical ball milling.
- Published in Chemistry-news, Departmental News, News, Research News
Significant Advancement in Analytical Detection of NFZ by the Department of Chemistry and RARE Lab
The Department of Chemistry and RARE Lab are excited to announce a groundbreaking advancement in the field of analytical detection. Researchers Dr Rajapandiyan Panneerselvan, Asst. Professor and Ph.D scholars, Ms Arunima Jinachandran and Ms Jayasree Kumar have developed a novel method for detecting nitrofurazone (NFZ) using three-dimensional silver nanopopcorns (Ag NPCs) on a flexible polycarbonate membrane (PCM) in their paper “Silver nanopopcorns decorated on flexible membrane for SERS detection of nitrofurazone” published in Microchimica Acta. This innovative technique leverages the power of surface-enhanced Raman spectroscopy (SERS) to provide a highly sensitive and practical solution for detecting NFZ on various surfaces, including fish.
Nitrofurazone (NFZ) is an antibiotic commonly used in veterinary medicine that poses significant health risks if residues enter the food chain. Despite regulatory bans, its illegal use continues, necessitating highly sensitive detection methods. While effective, traditional methods such as high-performance liquid chromatography and mass spectrometry are often costly and labor-intensive. The new SERS-based method offers a more efficient and straightforward alternative.
Abstract
The synthesis of three-dimensional silver nanopopcorns (Ag NPCs) onto a flexible polycarbonate membrane (PCM) for the detection of nitrofurazone (NFZ) on fish surfaces by surface-enhanced Raman spectroscopy (SERS) is presented. The proposed flexible Ag-NPCs/PCM SERS substrate exhibits significant Raman signal intensity enhancement with a measured enhancement factor of 2.36 × 10^6. This enhancement is primarily attributed to the hotspots created on Ag NPCs, which include numerous nanoscale protrusions and internal crevices distributed across the surface. The detection of NFZ using this flexible SERS substrate demonstrates a low limit of detection (LOD) of 3.7 × 10^−9 M and uniform, reproducible Raman signal intensities with a relative standard deviation below 8.34%. The substrate also exhibits excellent stability, retaining 70% of its efficacy even after 10 days of storage. Notably, the practical detection of NFZ in tap water, honey water, and fish surfaces achieves LOD values of 1.35 × 10^−8 M, 5.76 × 10^−7 M, and 3.61 × 10^−8 M, respectively, highlighting its effectiveness across different sample types. The developed Ag-NPCs/PCM SERS substrate presents promising potential for the sensitive SERS detection of toxic substances in real-world samples.
Methodology
The synthesis involves creating silver nanopopcorns on a flexible polycarbonate membrane using a simple chemical method. The resulting Ag NPCs exhibit high surface roughness with numerous nanoscale features that enhance the Raman signal. This flexible substrate can easily collect samples from irregular surfaces without requiring extensive preparation.
This SERS substrate can detect NFZ in various real-world samples, including:
- Tap water
- Honey water
- Fish surfaces
The method’s sensitivity and ease of use make it a promising tool for ensuring food safety and monitoring environmental contaminants.
The Department believes this development will significantly impact public health by providing a reliable and accessible method for detecting harmful substances in the food chain.
- Published in Chemistry-news, Departmental News, News, Research News
Dr Chimoy Das’ Research Makes Latest Breakthrough in Material Science
The Department of Chemistry is thrilled to announce the paper “Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites”, published by Dr Chinmoy Das, Assistant Professor in the reputed Q1 Journal Chemical Science with an 8.4 Impact Factor. This groundbreaking research introduces a novel method for transforming crystalline phases into glasses through mechanochemical processes. This environmentally friendly and efficient method opens new doors for manufacturing glasses, revolutionising traditional processes. This remarkable research celebrates this extraordinary blend of chemistry, physics, and innovation!
Abstract
The first mechanochemically-induced hybrid organic-inorganic perovskites (HOIPs) crystal-to-glass transformation was reported as a quick, environmentally friendly, and productive method of making glasses. Within ten minutes of mechanical ball milling, the crystalline phase transformed into the amorphous phase, demonstrating glass transition behaviour as shown by thermal analysis methods. The microstructural evolution of amorphization was studied using time-resolved in situ ball-milling with synchrotron powder diffraction. The results indicated that energy may accumulate as crystal defects because the crystallite size reaches a comminution limit before the amorphization process is finished. The limited short-range order of amorphous HOIPs was discovered through total scattering experiments, and photoluminescence (PL) and ultraviolet-visible (UV-vis) spectroscopy were used to examine their optical characteristics.
Explanation of the research in layperson’s terms
Crystalline inorganic perovskites (general chemical formula is ABX3, where A and B are cations, and X is anion) are generally known for their unique optoelectronic applications, such as solar cells, photodetectors, and LEDs (light emitting diodes). In this research, Dr Das revealed hybrid materials comprised of organic linkers and inorganic nodes, which constitute hybrid organic-inorganic perovskites (HOIPs). The research demonstrated a rapid and environment-friendly (mechanochemically ball milling assisted) synthetic approach to transform the crystalline phase to its non-crystalline/amorphous phase. Interestingly, the amorphous phase of HOIPs showed temperature-dependent glass transition temperature (Tg) at very low temperatures, ~50 C. The structure of the HOIP glasses has been characterised through total-X-ray diffraction studies and pair-distribution functions. The crystalline and glassy HOIPs showed optical properties, which were studied by photoluminescence (PL) and ultraviolet-visible (UV-vis) spectroscopy.
Practical implementation/ social implications of your research
Through the mechanochemical approach, we prepared novel hybrid organic-inorganic perovskite (HOIP) glasses within ten minutes, showing the greater feasibility of processing the glass material for industrial implication. On the other hand, we also demonstrated that the HOIP glasses showed photoluminescence properties, which would enable us to fabricate the device for solar cells, photodetectors, LEDs and many more.
Collaborations
- Department of Materials Science and Metallurgy, University of Cambridge, United Kingdom.
The Department of Chemistry has established a research group at SRM University-AP, and the group has started to explore an emergent research area of crystal-glass composite materials towards the applications of atmospheric water harvesting, solid-state electrolytes, photovoltaics, and conversion of gaseous Carbon-dioxide molecules to industrially relevant liquids, such as methanol or ethanol.
Any interested candidate can reach out to Dr Chinmoy for exciting projects.
- Published in Chemistry-news, Departmental News, News, Research News
Inauguration of NMR Spectrometer Marks a Milestone in SRM University-AP’s Research Capabilities
In a significant leap forward for scientific research, SRM University-AP proudly inaugurated the 400 MHz NMR (Nuclear Magnetic Resonance) Spectrometer, procured through the DST-FIST program. This acquisition is a vital component of the broader DST FIST project, which has been awarded to the Department of Chemistry at SRM University- AP with a budget of 2.20 crores.
As part of the project, the Department of Chemistry was recommended a 400 MHz NMR spectrometer by DST, which will play a crucial role in enhancing our expertise and aiding in achieving the proposed objectives. This state-of-the-art equipment is capable of characterising organic, inorganic, and biomolecules, enabling us to conduct comprehensive analyses and advance our understanding of complex chemical systems.
The ceremony, graced by esteemed guests, university dignitaries, faculties, and students, heralded a new era of scientific exploration and innovation. Prof. Lakshmi Kantam Mannepalli, Dr B P Godrej Distinguished Professor, ICT Mumbai, Chief Guest at the event, expressed, ” The inauguration of the 400 MHz NMR Spectrometer heralds a new era of precision and insight in scientific exploration. This instrument will unravel the mysteries of molecular structures and catalyse groundbreaking discoveries in the realm of chemistry and beyond.”
Dr S Mannathan, Associate Professor, Department of Chemistry, extended a warm welcome to the esteemed gathering and offered an insightful demonstration of the equipment’s operation, highlighting its advanced features and functionalities.
Prof. Manoj K Arora, Vice Chancellor, conveyed heartfelt congratulations to the team for this remarkable accomplishment, emphasising the transformative impact the new NMR Spectrometer will have on research and academic pursuits within the Department of Chemistry and beyond.”
Prof D Narayana Rao, Executive Director – Research, SRM Group of Institutions, emphasised, “The addition of this advanced equipment will significantly enhance the research capabilities, opening new avenues for exploration and discovery.”
V S Rao, Advisor, lauded the team for their achievement, stating, “This state-of-the-art equipment embodies our commitment to providing cutting-edge resources for our researchers and fostering a culture of innovation and discovery.”
Dr Pardha Saradhi Maram, Head of the Department of Chemistry, expressed his gratitude to all present and extended heartfelt thanks for their support and encouragement.
The acquisition of the 400 MHz NMR Spectrometer represents a significant advancement in scientific instrumentation, enabling researchers to delve deeper into molecular structures, chemical compositions, and dynamic processes. The Equipment will not only benefit the Department of Chemistry and Physics but also serve as a valuable resource for faculties and students across various disciplines.
The university has already trained 70 to 80 individuals in the operation of this equipment and is planning to organise a workshop for students and faculties from different universities, offering them the opportunity to leverage this advanced technology for their research and academic pursuits.
- Published in Chemistry-news, Departmental News, News, Research News