The Department of Chemistry is thrilled to announce the paper “Mechanochemically-induced glass formation from two-dimensional hybrid organic-inorganic perovskites”, published by Dr Chinmoy Das, Assistant Professor in the reputed Q1 Journal Chemical Science with an 8.4 Impact Factor. This groundbreaking research introduces a novel method for transforming crystalline phases into glasses through mechanochemical processes. This environmentally friendly and efficient method opens new doors for manufacturing glasses, revolutionising traditional processes. This remarkable research celebrates this extraordinary blend of chemistry, physics, and innovation!
Abstract
The first mechanochemically-induced hybrid organic-inorganic perovskites (HOIPs) crystal-to-glass transformation was reported as a quick, environmentally friendly, and productive method of making glasses. Within ten minutes of mechanical ball milling, the crystalline phase transformed into the amorphous phase, demonstrating glass transition behaviour as shown by thermal analysis methods. The microstructural evolution of amorphization was studied using time-resolved in situ ball-milling with synchrotron powder diffraction. The results indicated that energy may accumulate as crystal defects because the crystallite size reaches a comminution limit before the amorphization process is finished. The limited short-range order of amorphous HOIPs was discovered through total scattering experiments, and photoluminescence (PL) and ultraviolet-visible (UV-vis) spectroscopy were used to examine their optical characteristics.
Explanation of the research in layperson’s terms
Crystalline inorganic perovskites (general chemical formula is ABX3, where A and B are cations, and X is anion) are generally known for their unique optoelectronic applications, such as solar cells, photodetectors, and LEDs (light emitting diodes). In this research, Dr Das revealed hybrid materials comprised of organic linkers and inorganic nodes, which constitute hybrid organic-inorganic perovskites (HOIPs). The research demonstrated a rapid and environment-friendly (mechanochemically ball milling assisted) synthetic approach to transform the crystalline phase to its non-crystalline/amorphous phase. Interestingly, the amorphous phase of HOIPs showed temperature-dependent glass transition temperature (Tg) at very low temperatures, ~50 C. The structure of the HOIP glasses has been characterised through total-X-ray diffraction studies and pair-distribution functions. The crystalline and glassy HOIPs showed optical properties, which were studied by photoluminescence (PL) and ultraviolet-visible (UV-vis) spectroscopy.
Figure 1. Single crystal structures of (A) (S-NEA)2PbBr4 and (B) (rac-NEA)2PbBr4. Pb, Br, C, N and H atoms are represented by purple, brown, pink, blue, and grey colours, respectively. (C) Schematic illustration of the microstructural evolution on 2D HOIPs upon ball-milling. (D) UV-Vis and (E) photoluminescent properties of crystalline (S-NEA)2PbBr4 (purple) and glassy (S-NEA)2PbBr4 (blue) HOIPs.
Practical implementation/ social implications of your research
Through the mechanochemical approach, we prepared novel hybrid organic-inorganic perovskite (HOIP) glasses within ten minutes, showing the greater feasibility of processing the glass material for industrial implication. On the other hand, we also demonstrated that the HOIP glasses showed photoluminescence properties, which would enable us to fabricate the device for solar cells, photodetectors, LEDs and many more.
Collaborations
- Department of Materials Science and Metallurgy, University of Cambridge, United Kingdom.
The Department of Chemistry has established a research group at SRM University-AP, and the group has started to explore an emergent research area of crystal-glass composite materials towards the applications of atmospheric water harvesting, solid-state electrolytes, photovoltaics, and conversion of gaseous Carbon-dioxide molecules to industrially relevant liquids, such as methanol or ethanol.
Any interested candidate can reach out to Dr Chinmoy for exciting projects.