Dr Jaidev Kaushik, Assistant Professor from the Department of Chemistry, has introduced an innovative method for converting CO₂ emissions into valuable products like acetic acid, offering a sustainable solution to combat climate change. His groundbreaking research has been published in the Chemical Engineering Journal under the title, Hydrogen Peroxide Mediated Thermo-Catalytic Conversion of Carbon Dioxide to C1-C2 Products over Cu(0).
A Brief Abstract:
The global challenge concerning CO2 conversion to valuable products is anticipated to play a critical role towards net zero carbon emissions. Thermal CO2 reduction is advantageous in terms of higher conversion rates, selectivity, and already-established industrial thermal instruments for scalability. However, the method is energy-intensive, a hindrance to sustainably practical adoption. Herein, we present a comprehensive study of H2O2-mediated thermal CO2 conversion in the presence of dendritic zerovalent copper (d-ZCu) in a batch-type reactor, yielding C1 and C2 carbon products, with acetic acid (AcOH) as the major product (achieving an optimized yield of approximately 0.98 M and a selectivity of around 97% at near-ambient conditions of 25-150°C and 1-15 bar), along with trace amounts of methanol and ethanol, and carbon monoxide (CO) as a gaseous product. The reaction parameters, including temperature, time, pressure, and concentrations, were optimized to gain better insight into the reaction. To further explore the feasibility of the process, experiments were conducted in a continuous flow-packed bed reactor using similar parameters as those in the batch reactor, where CO was identified as the primary product of CO2 reduction. For advanced real-life applicability, the as-emitted exhaust gases from diesel and petrol engines, as sources of anthropogenic CO2, were utilized to establish the practical applicability of the proposed method.
Explanation in Layperson’s Terms:
In our work, we found a way to convert CO2, a gas that contributes to climate change, into useful products. We used hydrogen peroxide and a special type of copper catalyst (zerovalent and dendritic shaped) to change CO2 into things like acetic acid (used in vinegar), methanol, ethanol, and carbon monoxide. The main product we made was acetic acid, and the process worked well at lower temperatures and pressures, which means it used less energy. To see if this could be useful in real life, we tested it with CO2 coming from car exhaust, including diesel and petrol engines, and found that it could help reduce pollution. This shows that our method could be a practical way to reduce CO2 emissions from everyday sources.
Practical Implementation and Social Implications:
The practical implementation of our research offers a promising solution for reducing CO2 emissions by converting this harmful gas into valuable products like acetic acid, methanol, ethanol, and carbon monoxide. We used hydrogen peroxide and a dendritic zerovalent copper to operate our method at lower temperatures and pressures, making it more energy-efficient than traditional CO₂ reduction techniques. The implementation of this approach may not only help industries reduce their carbon footprint but also provide economic value by synthesizing widely used products. A key social benefit is its potential to capture and convert CO2 emissions from everyday sources, such as car exhaust, demonstrating how this method can help reduce pollution in urban environments. Overall, this technology supports the global effort to achieve net-zero carbon emissions, offering a practical and scalable solution for industries and everyday applications alike.
Collaborations:
Dr Sumit Kumar Sonkar (MNIT Jaipur, India)
Future Research Plans:
- The adsorption/photodegradation-assisted quick and efficient removal of next generation advanced pollutants such as microplastic, pesticides, pharmaceutical waste, etc. by hydrophobic carbon aerogel and their doped and functionalized versions.
- Utilizing waste derived heterogeneous catalysts in organic transformation reactions.
- Selective sensing of toxic metal ions/biomarkers/biomolecules using fluorescent nanomaterials.
- Upcycling of carbonates/CO2 via photo/thermal assisted reactions to get C1 and C2 hydrocarbons (green fuel).
The link to the article
https://www.sciencedirect.com/science/article/abs/pii/S1385894724082779