The Department of chemistry has always been a dynamic space for innovative and inspiring research. Recently, Assistant Professor Dr Nimai Mishra published his fifteenth research paper from SRM university-AP as a corresponding author. The paper is titled Post-synthesis Treatment with Lead Bromide for Obtaining Near Unity Photoluminescence Quantum Yield and Ultra-Stable Amine Free CsPbBr 3 Perovskite Nanocrystal and is published in the Q1 journal, The Journal of Physical Chemistry C with an impact factor of 4.2. The research group is comprised of Dr Mishra’s PhD students Mr Syed Akhil, Dr V G Vasavi Dutt, and Mr Rahul Singh. This is the group’s fifth consecutive article published in the American Chemical Society.
About the article
The article reports Ultra-Stable and Near Unity Photoluminescence Quantum Yield Amine Free CsPbBr 3 Perovskite Nanocrystal Post-synthesis Treatment with Lead Bromide. Herein, the researchers have introduced a simple lead bromide (PbBr 2 ) post-treatment process to achieve the near-unity PLQY (>95 %) in amine-free CsPbBr 3 PNCs. Furthermore, PbBr 2 treatment enables these materials to drastically improve stability in different environmental conditions (polar solvents, light, and heat). In addition, a green-emitting down- converted light-emitting diode was fabricated using PbBr 2 treated amine-free CsPbBr 3 PNCs, which shows its considerable prospects for display applications. Thus, the results of the research will promote these PbBr 2 treated amine-free inorganic perovskite nanocrystals for commercial development in optoelectronic applications.
Explanation of the research
Cesium lead halide perovskite nanocrystals (PNCs) have been the flourishing area of research in the field of photovoltaic and optoelectronic applications because of their excellent optical and electronic properties. Mainly, cesium lead bromide (CsPbBr 3 ) NCs with bright green photoluminescence (PL) and narrow full-width at half-maximum (FWHM) of < 25 nm is the most desirable for television displays and green-emitting LEDs. Improving the photoluminescence quantum yields (PLQYs) and optimizing the stability have been challenging tasks to promote cesium lead halide (CsPbX3; X=Cl, Br and I) perovskite nanocrystals (PNCs) for real optoelectronic applications. In recent years, the amine- free synthesis route has become an option for making stable CsPbX 3 PNCs.