Recent News

Dr Jaidev Kaushik, Assistant Professor from the Department of Chemistry, has introduced an innovative method for converting CO₂ emissions into valuable products like acetic acid, offering a sustainable solution to combat climate change. His groundbreaking research has been published in the Chemical Engineering Journal under the title, Hydrogen Peroxide Mediated Thermo-Catalytic Conversion of Carbon Dioxide to C1-C2 Products over Cu(0).

A Brief Abstract:

The global challenge concerning CO2 conversion to valuable products is anticipated to play a critical role towards net zero carbon emissions. Thermal CO2 reduction is advantageous in terms of higher conversion rates, selectivity, and already-established industrial thermal instruments for scalability. However, the method is energy-intensive, a hindrance to sustainably practical adoption. Herein, we present a comprehensive study of H2O2-mediated thermal CO2 conversion in the presence of dendritic zerovalent copper (d-ZCu) in a batch-type reactor, yielding C1 and C2 carbon products, with acetic acid (AcOH) as the major product (achieving an optimized yield of approximately 0.98 M and a selectivity of around 97% at near-ambient conditions of 25-150°C and 1-15 bar), along with trace amounts of methanol and ethanol, and carbon monoxide (CO) as a gaseous product. The reaction parameters, including temperature, time, pressure, and concentrations, were optimized to gain better insight into the reaction. To further explore the feasibility of the process, experiments were conducted in a continuous flow-packed bed reactor using similar parameters as those in the batch reactor, where CO was identified as the primary product of CO2 reduction. For advanced real-life applicability, the as-emitted exhaust gases from diesel and petrol engines, as sources of anthropogenic CO2, were utilized to establish the practical applicability of the proposed method.

Explanation in Layperson’s Terms:

In our work, we found a way to convert CO2, a gas that contributes to climate change, into useful products. We used hydrogen peroxide and a special type of copper catalyst (zerovalent and dendritic shaped) to change CO2 into things like acetic acid (used in vinegar), methanol, ethanol, and carbon monoxide. The main product we made was acetic acid, and the process worked well at lower temperatures and pressures, which means it used less energy. To see if this could be useful in real life, we tested it with CO2 coming from car exhaust, including diesel and petrol engines, and found that it could help reduce pollution. This shows that our method could be a practical way to reduce CO2 emissions from everyday sources.

Practical Implementation and Social Implications:

The practical implementation of our research offers a promising solution for reducing CO2 emissions by converting this harmful gas into valuable products like acetic acid, methanol, ethanol, and carbon monoxide. We used hydrogen peroxide and a dendritic zerovalent copper to operate our method at lower temperatures and pressures, making it more energy-efficient than traditional CO₂ reduction techniques. The implementation of this approach may not only help industries reduce their carbon footprint but also provide economic value by synthesizing widely used products. A key social benefit is its potential to capture and convert CO2 emissions from everyday sources, such as car exhaust, demonstrating how this method can help reduce pollution in urban environments. Overall, this technology supports the global effort to achieve net-zero carbon emissions, offering a practical and scalable solution for industries and everyday applications alike.

Collaborations:

Dr Sumit Kumar Sonkar (MNIT Jaipur, India)

Future Research Plans:

• The adsorption/photodegradation-assisted quick and efficient removal of next generation advanced pollutants such as microplastic, pesticides, pharmaceutical waste, etc. by hydrophobic carbon aerogel and their doped and functionalized versions.
• Utilizing waste derived heterogeneous catalysts in organic transformation reactions.
• Selective sensing of toxic metal ions/biomarkers/biomolecules using fluorescent nanomaterials.
• Upcycling of carbonates/CO2 via photo/thermal assisted reactions to get C1 and C2 hydrocarbons (green fuel).

The link to the article

https://www.sciencedirect.com/science/article/abs/pii/S1385894724082779

On November 30, 2024, the Department of Chemistry, in collaboration with the Directorate of Admissions, hosted ChemZeal 3, a flagship event that showcased the ever-expanding scope of chemistry in today’s world. The event was graced by prominent personalities, including the Chief Guest, Prof. Vijayamohanan Pillai, Dean of Research & Development at IISER Tirupati, and Dr Veerababu, Director of Cathode, GODI India Pvt. Ltd., Hyderabad, who served as the resource person.

The event began with a welcome address by the convener, Dr Satheesh Ellipilli, who provided an insightful overview of the programme and reflected on the immense success of the previous editions, ChemZeal 1 and 2. He expressed excitement about the growth of the event and its contribution to advancing the knowledge and application of chemistry in various fields.

Following the welcome, the Head of the Department of Chemistry delivered an inspiring speech, offering a comprehensive overview of the department. Dr Pardha Saradhi Maram, Associate Professor and Head highlighted the department’s commitment to academic excellence, research innovation, and fostering an environment where students can explore the transformative power of chemistry.

One of the major highlights of the event was the launch of the “Post a Q” portal by Vice Chancellor, Prof. Manoj K Arora. The portal aims to provide a platform for students and researchers to ask questions and seek solutions in the realm of chemistry. During the launch, Prof. Arora remarked, “Chemistry is such a wonderful science that, no matter what you think of, you will find chemistry in it.” This statement underscored the far-reaching impact of chemistry on everyday life and innovation.

The keynote address by the Chief Guest, Prof. Vijayamohanan Pillai, focused on generating and storing clean energy. He discussed the pivotal role that chemistry plays in developing sustainable solutions for energy storage and generation, from battery technologies to renewable energy sources. Prof. Pillai’s talk resonated with the audience, particularly in the context of the growing need for clean energy in the face of global environmental challenges.

The resource person, Dr Veerababu, shared valuable insights into cathode materials and their applications in the energy sector. His expertise in battery technology and his role at GODI India added depth to the discussions, providing students and faculty with a practical perspective on the industry’s current advancements.

ChemZeal 3 successfully fostered a spirit of collaboration and intellectual curiosity, highlighting the dynamic nature of chemistry and its potential to address some of the world’s most pressing issues. The event concluded with a vote of thanks, acknowledging the contributions of all the speakers, participants, and organisers who made the day a resounding success.

In an inspiring collaboration, Prof. G S Vinod Kumar and Prof. Sheela Singh from the Department of Mechanical Engineering, Prof. Ranjit Thapa from the Department of Physics, and Dr Rajapandiyan Panneerselvam from the Department of Chemistry at SRM University – AP, along with PhD scholars Ms Harsha K and Ms Arunima J, have co-authored a compelling paper titled “Innovative Approaches to Enhancing the Tarnish Resistance of Silver Alloys.” This groundbreaking research focuses on developing new silver alloys that resist tarnishing, enhancing durability and aesthetic appeal for applications in the jewellery industry. Together, they are paving the way for innovative solutions that blend science with artistry.

Abstract

Silver and its alloys undergo tarnishing with time, which is a black stain on the surface due to the formation of Ag2S. Developing a tarnish resistant Ag alloy was attempted by alloying Ag with elements that form a passive oxide layer on the surface. Germanium is proven to provide better tarnish resistance to sterling silver alloy (92.5wt.% pure) which is available under the trade name of Argentium©. The present work investigates the tarnish resistance behaviour of sterling silver alloy (92.5wt.% pure) containing various additions of Copper, Zinc, Germanium, Aluminium, Beryllium, Titanium, Zirconium, and Magnesium. The alloys were prepared by melting and casting route, followed by Passivation Heat Treatment (PHT) to create a stable and continuous oxide layer. The temperature for PHT was optimized using thermogravimetry analysis (TGA) of the alloys prepared. An accelerated tarnish test was carried out to investigate the tarnishing behaviour of alloy samples obtained before and after PHT. The samples were characterized using XRD, SEM-EDX, TG-DSC, micro-Raman Spectroscopy, and XPS. The change in reflectance of the samples after the tarnish test is determined using UV-visible reflectance spectroscopy. The mechanism behind the tarnish resistance was derived using Density Functional Theory (DFT) by comparing sulphur (S2) and Oxygen (O2) adsorption energies (BE) of the alloying elements.

Explanation of the Research in layperson’s terms

Age-old silver pieces are found in different colours ranging from light yellow(silver Jewellery pieces after a few weeks of usage) to black(archaeological silver pieces). They look different in terms of the metallic white colour and lustrous appearance from fresh silver. This demeans silver and thus affects its market. The major cause of the staining of silver is the interaction of individual silver particles with some elements found common in the atmosphere. We work on the prevention of this staining of silver. For the study, silver is incorporated with other elements which makes silver less interacting with staining elements in the atmosphere. These additional elements create a layer over silver so that it is protected. The appropriate elements are identified by using modelling using computer software. After obtaining appropriate elements, the experimental trials are also done with the same elements until stainless silver is obtained. Then, what happens to the added elements inside silver is also studied by using modern microscopic technics.

Practical/Social Implications of the Research

The major application of the invention is in the jewellery industry. The problem of tarnishing is an age-old threat in jewellery making. The alloys we proposed could be used to make quality silver jewellery/articles that can sustain the colour and lustre for a longer period. This will stop the hesitation from jewellery designers and industries to try intricate designs in silver and find a better market for them. The alloys based on the proposed composition show good grain refinement and thus high hardness. This strengthens the soft silver and improves the range of its applications from low hardness articles to high. The alloys based on the proposed composition have high tensile strength. They deform plastically for a wide range of stress values and will not break easily.

Collaborations:

Waman Hari Pethe & Sons Jewellery

Future Research Plans:

1. Corrosion studies of silver alloys to understand the behaviour in solutions having compositions similar to that of sweat.

2. Study of mechanical properties of silver alloys to develop workable alloys of sterling silver which could be used for jewellery manufacturing

3. Identification of elements having better oxide layer formation when alloyed with silver, by using computational techniques and experimental studies of their properties.

Link to the article:
https://www.sciencedirect.com/science/article/pii/S2238785424024633

As water scarcity becomes an increasingly pressing issue, innovative solutions like atmospheric water harvesting (AWH) are being explored to provide sustainable access to fresh water. Dr Chinmoy Das, Assistant Professor from the Department of Chemistry and his research scholar Mr Sushant Wakekar have in their research paper titled, “Deciphering the functions of Metal-Organic Frameworks and their derived composites towards Atmospheric Water Harvesting: A comprehensive Review” analysed the crucial role of metal-organic frameworks (MOFs) and their composites in enhancing the efficiency of AWH systems.

Abstract

To address water scarcity globally, recently atmospheric water harvesting (AWH) has emerged as an intriguing and sustainable solution. This comprehensive review critically investigates how diversity in metal-organic frameworks (MOFs) and their composite materials shapes the effectiveness and practicality of AWH technologies. These materials range from pristine MOFs to functionalized MOFs-based composites to attain the sophisticated hydrophilic behavior to perform as water harvesters. The multifaceted effects of MOFs and their composite materials on the kinetics of sorption and condensation, the feasibility of water uptake and release, the overall performance of the materials, the theoretical understanding of water uptake, and various instrumentation techniques have been demonstrated in this comprehensive review. It contributes to the ongoing discourse on sustainable water sourcing by emphasizing the pivotal role of materials diversity in shaping the future of AWH technologies.

Explanation of Research in layperson’s terms:

This review article explains how AWH technology, which captures water from the air, could provide sustainable solutions for water scarcity. We focus on advanced materials called MOFs and their ability to improve AWH efficiency. By analyzing different types of MOFs and MOF-based composites, we explore how they enhance water absorption and release, potentially making AWH more practical and effective for real-world use.

Practical/Social Implications of the Research:

This technology could have far-reaching social impacts by offering a reliable water source for communities in arid or remote areas, reducing reliance on traditional, often costly water sources, and strengthening resilience to climate change.

Future Research Plans:

To design and synthesis a material which can work with a minimum relative humidity (%RH) and design a suitable prototype for it.

Link to the Article

https://www.sciencedirect.com/science/article/pii/S2214993724003002